Yang G, Zhang X, Jiang Q, Huan S, Meng L, Qiu L et al.
Conventional fruit and vegetable packaging films are often not only environmentally unsustainable but also lack effective antibacterial activity. To address this, we developed a multifunctional composite film (C@CuSAP) by incorporating carboxymethyl cellulose (CMC)-stabilized copper sulfide nanop...
Huang R, Zhang X, Liao X, Bai R, Wu X, Xiang J et al.
In situ Transmission Electron Microscopy (TEM) provides powerful insights into the reaction mechanisms of Lithium-Sulfur (Li-S) batteries. However, distinguishing intrinsic electrochemical behaviors from artifacts induced by high-energy electron beam irradiation remains a critical challenge. Here...
Pellegrino S, Martínez-Marco P, Moreno-Andrés J, Bautista-Chamizo E, Amat AM, Minero C et al.
This work studied the effect of pH, [O2], H2O2 external addition, chelating agents, common anions, transition metals, and produced toxicity, in the process Cu-(II)/NH2OH (employing benzoate as a probe). It was observed that (i) acidification by NH2OH·HCl addition hindered the process signifi...
Nanotechnology, science and applications··PMID: 41710346
Alqahtani A, Mahmoud NMR, Rehman S, Ahmed SB
Sustainable nanotechnology requires synthesis approaches that are environmentally benign while maintaining high efficiency, yield, and functionality. Plant-mediated synthesis combined with advanced heating techniques offers a promising route to achieve these goals.Phyto-copper oxide nanoparticles...
Dried bakery products are produced using several different input materials derived from baked goods, breakfast cereals, tortillas, and confections, depending on the geography and regional producers. Therefore, the physical characteristics and nutrient composition can vary between processing plant...
Contributions to mineralogy and petrology. Beitrage zur Mineralogie und Petrologie··PMID: 41709956
Soderman CR, Weller OM
Trace element ratios in arc magmas are widely used to infer petrogenetic conditions, particularly those associated with porphyry-forming versus barren systems. However, quantitatively linking whole-rock signatures to pressure, water content, or redox conditions remains challenging, as trace eleme...
Schneider LN, Csapo ER, Knuplez T, Keppner F, Ignat'ev NV, Finze M et al.
A series of bis(trifluoromethyl)amido coinage metal(I) complexes were synthesized in yields of 52-93%. This includes N-heterocyclic carbene (NHC) complexes of copper(I), silver(I), and gold(I). In addition, the complex [(Ph3P)Au{N(CF3)2}] was obtained in 70% yield. The complexes are thermally rob...
The American journal of Chinese medicine··PMID: 41709570
Liang HH, Jia LL, Tang K, Xue R, Nie RR, Chen JN et al.
Colorectal cancer (CRC) exhibits high mortality due to tumor cell dissemination. Surgical resection combined with chemotherapy is the primary treatment, but chemoresistance often limits its efficacy against metastasis. Cuproptosis, a novel cell death mechanism regulating mitochondrial and lipid m...
Diabetic wound management represents a substantial clinical challenge owing to the deteriorative tissue microenvironment including the excessive reactive oxygen species (ROS), persistent inflammation, and potential bacterial infection. To address these issues, herein, a hybrid hydrogel scaffold (...
Luminescence : the journal of biological and chemical luminescence··PMID: 41709091
Purnima, Singh P
We have reported perylene tetra-(alkoxycarbonyl) (PTAC) derivative PTE-EA functionalized with tetraoctylester chains at the peri-positions and an electron-donating group 2-aminoethanol (2-AE) at the mono bay-position. PTE-EA showed colorimetric and fluorescence turn-on response for detection of c...
Environmental geochemistry and health··PMID: 41709064
Gezer D, Tekingündüz E, Özdemir A, Jabrayilov N
Gastric cancer remains one of the most common and deadly malignancies worldwide. Trace elements are gaining increasing interest due to their dual roles as both essential nutrients and potential carcinogens. This study aimed to compare trace element concentrations in gastric cancer tissues with he...
Cross-coupling of aryl boronic esters forms a cornerstone of how chemists make molecules. More recently, enantiomerically enriched boronic esters have shown great promise in modular synthesis as versatile building blocks for the rapid construction of diverse molecules. A significant challenge in ...
Comparative biochemistry and physiology. Toxicology & pharmacology : CBP··PMID: 41707821
Shoman N, Solomonova E, Akimov A
The toxic effect of zinc oxide (ZnO NPs) and copper oxide (CuO NPs) nanoparticles on natural communities of Black Sea picophytoplankton was investigated during a year-long cycle of in-situ experiments. The results revealed pronounced seasonal and taxonomic specificity of toxicity. It was establis...
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy··PMID: 41707628
Singh R, Zeng Q, Han H, Nithin G, Sameera KS, Marques C et al.
Nanozymes have garnered growing interest due to their potential to act as substitutes for natural enzymes across a range of biomedical applications, including biosensing, catalysis, and immunoassays. Conventional approaches in biosensing application face several challenges due to their complicate...
The journal of physical chemistry. B··PMID: 41706822
Mori H, Tonogai S, Miyazaki Y, Hayashi A, Takayanagi M
Although polymerization and curing reactions govern the performance of advanced materials, their simulation remains challenging owing to the need for accurate, transferable potentials and the rarity of chemical events. Conventional reactive force fields such as ReaxFF require system-specific para...
Angewandte Chemie (International ed. in English)··PMID: 41706659
Wang K, Qi Y, Ding M, Tang Q, Shi X, Ye X et al.
This work reports a copper-catalyzed enantioselective S-alkylation of sulfenamides enabled by an amino-radical-transfer deboronation pathway. Chiral sulfilimines are obtained in high yields (up to 95%) and enantioselectivities (up to 98% ee) under mild conditions. An isomerizable bis(oxazoline) l...
Pouchucq L, Marcoleta AE, Becerra C, Bahamondes C, Lobos-Ruiz P
Metal contamination poses a global threat due to its widespread occurrence and high toxicity. Phytoremediation constitutes a preferred, environmentally rational approach for soil bioremediation. The identification and characterization of facilitating microorganisms, especially plant growth-promot...
The objective of this study was to evaluate the effect of copper (Cu) status on response to lubabegron fumarate (LUB; Experior, Elanco, Greenfield, IN) and adipose tissue physiology. Forty-eight Angus crossbred steers (469 ± 31 kg) were enrolled in a 77-day finishing stu...
At the micro-scale channel dimensions and relatively low Reynolds numbers, fluids can only mix through diffusion in a laminar flow state. This dependence on molecular diffusion significantly hinders the mixing performance of microfluidic chips. To address this issue and promote the application of...
Copper-based hybrid halides have attracted growing interest as tunable luminescent materials with diverse coordination architectures. Herein, a series of copper bromide-based hybrids were synthesized featuring distinct architectures: (MEP)(Cu2Br4)0.5 (M1), (MEP)(Cu4Br6)0.5 (M2), and (MEP)8(Cu4Br6...
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